Are you able to receive emails but not send?
If you can receive mail but aren't able to send this means one thing.....
Your internet provider is attempting to block you from using anyone's outgoing
mail servers but their own. Many major ISPs are blocking outgoing
emails to prevent you from using their
internet connection for spamming purposes.
You will still be able to
send emails, but you will need to change your outgoing mail (SMTP) to use port 26 or 465.